Catenanes, rotaxanes, and knots.

  • 192 Pages
  • 4.60 MB
  • 7165 Downloads
  • English
by
Academic Press , New York
Catenanes., Rotax
StatementTranslated by J. Boeckmann.
SeriesOrganic chemistry; a series of monographs,, v. 22, Organic chemistry (New York, N.Y.) ;, v. 22.
Classifications
LC ClassificationsQD471 .S35513 1971
The Physical Object
Paginationx, 192 p.
ID Numbers
Open LibraryOL4767471M
LC Control Number78127702

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Details Catenanes, rotaxanes, and knots. FB2

This journey through the fascinating world of molecular topology focuses on catenanes, rotaxanes and knots, their synthesis, properties, and applications and the theory of interlocking and interpenetrating molecules. Nearly one hundred years of progress have passed since Willstatter's speculative vision of a molecule consisting.

Purchase Catenanes, Rotaxanes, and Knots - 1st Edition. Print Book & E-Book. ISBNBook Edition: 1. Molecular Catenanes, Rotaxanes and And knots. book A Journey Through the World of Molecular Topology J.-P. Sauvage, C.

Dietrich-Buchecker (Eds.) This journey Catenanes the fascinating world of molecular topology focuses on catenanes, rotaxanes and knots, their synthesis, properties, and applications and the theory of interlocking and interpenetrating molecules. Additional Physical Format: Online version: Schill, Gottfried.

Catenanes, rotaxanes, and knots. New York, Academic Press, (OCoLC) Document Type. Book chapter Full text access 18 - Investigations of the Synthesis of Knots, Double Wound Catenanes and Rotaxanes, and Higher Linear Catenanes Pages Download PDF.

Catenanes, Rotaxanes, and Knots | GOTTFRIED SCHILL (Eds.) | download | B–OK. Download books for free. Catenanes books. This journey through the fascinating world of molecular topology focuses on catenanes, rotaxanes and knots, their synthesis, properties, and applications and the theory of interlocking and interpenetrating molecules.

Nearly one hundred years of progress have passed since Willstatter's speculative vision of a molecule consisting of two interlinked rings. But even today the synthesis of such. Pseudorotaxanes and Rotaxanes Incorporating Macrocyclic Polyethers and Secondary Dialkylammonium Salts Pseudorotaxanes.

and knots. book Catenanes. Rotaxanes. and Knots Incorporating Catenanes and Rotaxanes Incorporating Amide Recognition Sites Catenanes and Rotaxanes Incorporating Cyclodextrins 8 Amide-Based Catenanes. A good pictorial representation of catenanes, rotaxanes and knots is shown on page In Summer when I rotaxanes attending an IUPAC Congress where Stoddart gave a lecture, I considered having "Molecule of the Year" reported in our journal Molecules every year, and a molecule in my mind was olympiadane (page of this book).

Mechanically interlocked molecules (often abbreviated to MIMs), 7 such as rotaxanes, 8 catenanes 9 and knots 10 were once considered synthetic chemical curiosities but are increasingly being turned toward useful application.

11 The opportunities offered in the construction of molecular machines by the relative motion of the constituent parts of. In book: Molecular Catenanes, Rotaxanes and Knots: A Journey Through the World of Molecular Topology (pp - ). As for rotaxanes, the general strategy for preparing catenanes in high yields is based on the template effect, which relies on the presence of molecular recognition sites between the components to be assembled [76].This kind of synthesis usually leads to ring components that carry two identical or different recognition sites (Figure 12).If the two recognition sites of each ring in a catenane.

This journey through the fascinating world of molecular topology focuses on catenanes, rotaxanes and knots, their synthesis, properties, and applications and the theory of interlocking and interpenetrating molecules.

Nearly one hundred years of progress have passed since Willstatter's speculative vision of a molecule consisting of two interlinked rings. The work of Gottfried Schill and other Freiburgers regarding catenanes, rotaxanes, and molecular knots are summarized.

Included are syntheses of the first catenane ever (A) and of the first (B) as well as the second catenane (C) without a ring within either constituent – a feature which makes them unique till today.C also is the only purely hydrocarbon catenane ever made.

Catenanes Assembled through π–π Stacking Interactions. Stoddart et al. carried out a seminal research program on the synthesis of catenanes and rotaxanes by exploiting the interactions of π-electron-rich (donor) and π-electron-deficient (acceptor) aromatic rings to direct the threading of molecular strands through macrocycles.

Lukin O., VöGtle F. () From Functionalised Catenanes, Rotaxanes and Knots to Higher Intertwined Assemblies. In: Gloe K. (eds) Macrocyclic Chemistry. Springer, Dordrecht. Genre/Form: Electronic books: Additional Physical Format: Print version: Schill, Gottfried. Catenanes, rotaxanes, and knots (DLC) (OCoLC)   Catenanes, Rotaxanes, and Knots Paperback – Novem by Gottfried Schill (Author) See all formats and editions Hide other formats and editions.

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Price New from Used from Kindle "Please retry" $ — — Hardcover "Please retry" — — $ Paperback "Please retry" $ Cited by: Book Editor(s): Prof. J.‐P. Sauvage. Faculté de Chimie Université Louis Pasteur 4, rue Blaise Pascal F‐ Strasbourg Cédex France Molecular Catenanes, Rotaxanes and Knots: A Journey Through the World of Molecular Topology.

Related; Information; Close Figure Viewer. Return to Figure. Previous Figure Next Figure. Caption. Catenanes, Rotaxanes, and Knots by G. Schill and a great selection of related books, art and collectibles available now at - Catenanes, Rotaxanes, and Knots.

A rotaxane is a mechanically interlocked molecular architecture consisting of a "dumbbell shaped molecule" which is threaded through a "macrocycle" (see graphical representation).The name is derived from the Latin for wheel (rota) and axle (axis).

The two components of a rotaxane are kinetically trapped since the ends of the dumbbell (often called stoppers) are larger than the internal. Catenanes, Rotaxanes, and Knots. Book Title:Catenanes, Rotaxanes, and Knots. This journey through the fascinating world of molecular topology focuses on catenanes, rotaxanes and knots, their synthesis, properties, and applications and the theory of interlocking and interpenetrating molecules.

Nearly one hundred years of progress have passed. Expanded definitions of rotaxanes and pseudorotaxanes, their components, and other terms concerning rotaxanes are given. The uniform classification and nomenclature principles for naming different types of rotaxanes and pseudorotaxanes are described and illustrated with examples.

Schill G. In Catenanes, Rotaxanes and Knots Academic Press: New-York, Google Scholar. Metal-directed synthesis – rotaxanes, catenanes, helicates and knots. Fraser Stoddart, Leonard F.

Description Catenanes, rotaxanes, and knots. PDF

Lindoy and Ian M. Atkinson No abstract available Download options Please wait Publication details From the book: Self Assembly in Supramolecular Systems Metal-directed synthesis – rotaxanes, catenanes, helicates and knots. Fraser. Pseudorotaxanes, Catenanes, Rotaxanes, and Knots Incorporating 7r-Electron-rich and Deficient Components Catenanes and Rotaxanes Incorporating Amide Recognition Sites in Their Components Catenanes and Rotaxanes Incorporating Cyclodextrins as their Macrocyclic Components Reflections and Opportunities References Here we describe the use of a dynamic covalent synthetic approach to improve the attachement of interlocked architectures to solid supports.

Although, dynamic covalent chemistry, and even more specifically disulfide exchange reactions have proved to be a successful synthetic strategy for the synthesis of catenanes and knots, comparatively few examples of its use for the synthesis of rotaxanes. This book is the first book devoted entirely to Hughes as an environmental activist and writer.

Catenanes, Rotaxanes, and Knots by G. Schill. Academic Press. Hardcover. VERY GOOD. Light rubbing wear to cover, spine and page edges. Very minimal writing or notations in margins not affecting the text. Possible clean ex-library copy, with their stickers and or stamps. Catenanes, rotaxanes and knots have become "Highlights " in supramolecular chemistry (1) thanks to more recent high yield syntheses via the use of supramolecular template effects (2).

Amide-based catenanes During work on the syntheses of basket-shaped host molecules (3) we unexpectedly found an extremely simple catenane synthesis in (4).

They are conceptually related to other mechanically interlocked molecular architectures, such as rotaxanes, molecular knots or molecular Borromean rings.

Recently the terminology "mechanical bond" has been coined that describes the connection between the macrocycles of a catenane. Catenanes have been synthesised in two different ways.Schill’s book Catenanes, Rotaxanes and Knots, written inis indispens-able for the topologist [4].

In addition to interesting theoretical considerations regarding interlocked rings and knots, it contains much information on the experimental approaches used by Lüttringhaus, Schill and their co-workers to.The valuable luminescence, magnetic, and catalytic properties of lanthanide cations are beginning to be exploited in conjunction with structurally exotic mechanically interlocked molecules (MIMs) such as rotaxanes, catenanes and knots.

This Minireview provides an account of this rapidly developing r .